Main directions of wear-resistant coatings on steel products in diffusion metallization

Authors

  • Y. G. Diachenko Donbass State Engineering Academy (DSEA), Kramatorsk

DOI:

https://doi.org/10.37142/2076-2151/2019-2(49)189

Keywords:

diffusion metallization; complete saturation of boron; chromium; aluminum; powder mixture; wear

Abstract

Diachenko Y. G. Main directions of wear-resistant coatings on steel products in diffusion metallization // Material working by pressure.  – 2019. – № 2 (49). - P. 189-194.

The theoretical analysis of the coatings obtained integrated saturation boron, chromium and aluminum in various mixtures with saturating position of their durability. Analyzed methods for preparing coatings simultaneously boron and chromium, boron and aluminum and boron, chromium, aluminum diffuse after metallization. It has been shown that one of the methods of applying the coatings is a complex diffuse saturation in powder mixtures based on boron. Revealed the composition of the surface layer with simultaneous saturation of boron and chromium, boron and aluminum and boron, chromium, aluminum, which allows to form on the surface of the high hardness coating parts. As a result, the theoretical analysis revealed that the layers on the basis of boron and chromium, obtained by different methods should be divided into three types: 1) iron-based boride (Fe, Cr) 2B, (Fe, Cr) B; 2) based on chromium boride (Cr, Fe) 2B, (Cr, Fe) B; 3) based on α - solid solution of chromium in the iron and boron with inclusions of boride. After saturation with boron and aluminum coatings are formed, which consist of three distinct layers: an outer layer with high content of aluminum, transition layer aluminum - iron, and an inner layer of boron - iron. The surface layer after diffusion metallization simultaneously boron, chromium and aluminum is composed of a mixture of small dispersed carbides and borides (HV 900 ... 1000) on a soft base. The introduction of the third component of the powder mixture allowed to form on the surface of the wear-resistant coating articles with desirable properties. The most promising is the complex process of saturation with boron, chromium and aluminum, when it is possible to minimize the energy costs of the process and to get the maximum effect of improving the wear resistance of metal.

Author Biography

Y. G. Diachenko, Donbass State Engineering Academy (DSEA), Kramatorsk

candidate of technical science, associate professor

References

Voroshnin L.G., Lyakhovich L.S. Boroning of steel. Moscow: Metallurgy. 1978, 240 p. (in Russian).

Borisenok G.V., Vasiliev L.A., Voroshnin L.G. et al. Chemical–thermal treatment of metals and alloys. Moscow: Metallurgy. 1981, 424 p. (in Russian).

Minkevich A.N. Chemical–thermal treatment of metals and alloys: textbook. Moscow: Mechanical Engineering. 1965, 492 p. (in Russian).

Modern methods of hardening the surfaces of machine parts: Analytical review. Scientific and technological progress in mechanical engineering. Ed. K.V. Frolov. Moscow: IMASH. USSR Academy of Sciences. 2009, 9.1, pp. 205–271. (in Russian).

Zablotsky V.K., Dyachenko Yu.G. Influence of the activator on the formation of wear–resistant borochromic coatings on tool carbon steels. Instrumentation and optimization of technological systems. Kramatorsk: DSEA. 2006, 19, pp. 213–217. (in Russian).

Guryev A.M., Garmaev A. Influence of borochroming parameters on the steel structure and physicomechanical properties of the diffusion layer. Polzunovs Bulletin. 2007, 3, pp. 28–34. (in Russian).

Stepanov M.S., Dombrovsky Yu.M., Pustovoit V.N. Diffusion saturation of carbon steel in the microarc heating mode. Metallurgy and heat treatment of metals. 2017, 1 (739), pp. 54–57. (in Russian).

Stepanov M.S., Dombrovsky Yu.M. Thermodynamic analysis of the reactions of formation of a carbide layer in steel during multi–arc saturation with molybdenum. Izvestiya. Ferrous Metallurgy. 2016, 59, 2, pp. 77–81. (in Russian).

Dombrovsky Yu.M., Stepanov M.S. Formation of a composite boride coating on steel during microarc chemical–thermal treatment. Izvestiya. Ferrous Metallurgy. 2015, 58, 3, pp. 214–215. (in Russian).

Denisyuk A.K., Zagulyaeva S.V., Potutkina E.N. The structure of borated layers in carbon steels. Machine tools and tools. 2010, 11, pp. 39–40. (in Russian).

Gadalov V.N. Physicomechanical, operational and relaxation properties of structural steels with boride, cyanide and galvanic coatings. Mechanics of composite materials and structures. 2011, 17, 4, pp. 592–598. (in Russian).

Lygdsnov B.D., Mosorov V.I., Mizhitov A.Ts. Studies of the phase composition and defective state of the gradient structures of boron steels 45 and 5KHNV. Bulletin of the East Siberian State Technological University. 2011, 1, pp. 25–31. (in Russian).

Biryukov V.P. Change in the properties of boron–containing coatings under the influence of a laser beam. Engineering Bulletin. 2012, 1, pp. 64 – 67. (in Russian).

Gadalov V.N., et al. Features of the structure and properties of boride diffusion layers, optimization of the technology for their production. Bulletin of the S-WSU. Ser. Technique and technology. Kursk. 2012, 2, 41, pp. 73–77. (in Russian).

Ishkov L.V. et al. Boride coatings for tillage organs of agricultural machinery: production, structure and wear resistance in real conditions. Proceedings of GOSNITI. 2012, T. 109, Part 2, pp. 124–131. (in Russian).

Gadalov V.N., Petrenko V.R., Lyakhov A.V. Chemical–thermal and electrophysical processing of alloys and coatings. Verlag. Publisher: LAP– LAMBERT. Germany. 2016, 250 p. (in Russian).

Gadalov V.N., et al. Investigation of the stress state in the surface layers of hypereutectoid steel after electrolysis boroning. Modern high technology. 2017, 2, pp. 12–16. (in Russian).

Gadalov V.N., et al. Increasing the durability of parts of traction chains of conveyors made of structural steels by electrolysis of boron. Prospects for the development of technology and processing in mechanical engineering. Kursk: S-WSU. 2017, pp. 64–72. (in Russian).

Voroshnin L. G., Aliiev A.A. Boroning from pastes. Astrakhan: ATTU. 2006, 287 p. (in Russian).

Gvozdev A.E., Starikov N.E., Zolotukhin V.I., Sergeev I.I., Sergeev A.I., Breki A.D. Technology of structural and operational materials: a textbook. Ed. A.E. Gvozdev. Tula: Publishing house of TulSU. 2016, 351 p. (in Russian).

Gadalov V.N., et al. Diffusion boride coatings on iron, steels and alloys (with an album of photos). Moscow: Course. 2012, 146 p. (in Russian).

Gadalov V.N. The effect of boron–containing coatings on the strength characteristics of steels. Proceedings of the 9th Int. practical conf. “Technology of repair, restoration and hardening of machine parts, mechanisms, equipment, tools and industrial equipment”. St. Petersburg: Publishing House of the Polytechnic University. 2007, Part 2, pp. 80–87. (in Russian).

Dombrovsky Yu.M., Stepanov M.S. New opportunities for surface alloying of steel in powder media. Engineering Bulletin. 2015, 8, pp. 79–81. (in Russian).

Koss E.V., Shevchenko I.M., Andryushchenko I.I. Borochromoal steel 45. Dep. in UkrNIINTI 12.09.88, 2314 Uk88. Odessa:OPI. 1988, 11 p. (in Russian).

Published

2019-12-22

How to Cite

Diachenko, Y. G. (2019). Main directions of wear-resistant coatings on steel products in diffusion metallization. Materials Working by Pressure, (2(49), 189–194. https://doi.org/10.37142/2076-2151/2019-2(49)189

Issue

Section

SECTION IV EQUIPMENT AND EQUIPMENT PRESSURE TREATMENT